This is topic Nitrate on a platter? in forum Film Handlers' Forum at Film-Tech Forum ARCHIVE.


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Posted by Leo Enticknap (Member # 534) on 08-28-2000, 03:17 PM:
 
Here's something worthy of the next Film-Tech training video download. My Russian neighbour showed me (or rather, translated for me) an article in 'Isvestia' today, which contained a report of a fire which gutted a cinema in Novosibirsk. The report said that the fire took place early in the morning and that one member of staff was seriously ill in hospital after inhaling toxic fumes, but that otherwise no-one was hurt.

It also contained the following information: (i) that the fire started in the projection box, (ii) that the cinema had been showing a special season of Soviet musicals from the 1930s, and (iii) that some very rare prints of these, supplied by the Russian State Film Archive, had been destroyed in the fire.

There was also a photo of the projection box - showing one projector (a Meopta I think) and a five-deck platter beside it.

Were they doing what I think they were doing???!!!
 


Posted by Bruce McGee (Member # 131) on 08-28-2000, 08:14 PM:
 
Kind of sounds like they were running a bit of nitrate there.

A few years ago, a friend and I started looking for a copy of a 1925 feature called "Conquest of Caanan" that was filmed here in downtown Asheville. It was presumed lost years ago, and the studio, Paramount, was not helpful. In fact, my friend was told by someone on the phone that they were not interested in that old stuff.

Persistance eventually paid off. My friend found that a print existed in Russia. The print they had was nitrate and had russian title cards. After some negotiations, and some city finances, we obtained a perfect new 10 reel print on safety stock. I am astounded at the sharpness of the print, cosidering it is a dupe. I assembled it onto 4 2000' reels. I could not read the Russian, so I went by the numbers at the bottom of each of the title cards. I must have gotten it right, as it was transferred in Atlanta to tape, and the print was returned to Asheville.
The film has been shown on cable TV several times with new english title cards translated from "old" Russian by a friend.

The print sat in City Hall for a couple of years before we got it back. It almost was thrown out during a city renovation project!

It is now here with my collection. I cant tell what the film stock is, but it sure smells good. I have run it on my Holmes once.

It is not a very good movie. It bombed on the first release.

The reason I mention this is because they do have a big collection of nitrate in Russia. I cant believe they would run the musical prints without taking major precautions.

Question: Could the nitrate sliding on the surface of the platter cause a spark that could ignite the film?

We all know about static with polyester bases.

Possibly just being such bad movies that they just burst into flames?


 


Posted by Mark Gulbrandsen (Member # 72) on 08-28-2000, 09:35 PM:
 
I'm assuming that the platter model was the Chernobyl MKV............
Mark
 
Posted by William Hooper (Member # 71) on 08-28-2000, 11:21 PM:
 
quote:
Were they doing what I think they were doing???!!!

If there was no evidence of magazines, & you're thinking they were running nitrate film on a platter....


 


Posted by John Pytlak (Member # 331) on 08-29-2000, 07:30 AM:
 
Kodak's web site has quite a bit of information on the properties and dangers of nitrate film:
http://www.kodak.com/country/US/en/motion/support/technical/storage3.shtml http://www.kodak.com/country/US/en/motion/about/environment/nitrate.shtml

------------------
John P. Pytlak, Senior Technical Specialist
Worldwide Technical Services, Entertainment Imaging
Eastman Kodak Company
Research Labs, Building 69, Room 7419
Rochester, New York, 14650-1922 USA
Tel: 716-477-5325 Fax: 716-722-7243
E-Mail: john.pytlak@kodak.com
 


Posted by Dave Cutler (Member # 515) on 08-29-2000, 10:39 AM:
 
I wouldn't be too suprised if they were doing what you think. Pretty scary stuff if you ask me. Man am I glad a don't work in a booth that requires a 'dead man door.'
 
Posted by John Wilson (Member # 269) on 08-29-2000, 02:28 PM:
 
I know that this topic doesn't have the flames coming out of the folder as it doesn't have at least 50 posts...but I really think it deserves the flames.

Oh those Russians aren't having too good a time of late, are they?
 


Posted by Leo Enticknap (Member # 534) on 09-04-2000, 05:14 PM:
 
There was a follow-up article in Friday's Isvestia, again kindly translated by my neighbour. They think the fire was caused by a Diesel generator malfunctioning and igniting 3 250-litre drums of fuel stored in the same plant room (:eek . The heat from this ignited 1968-vintage upholstery and carpets... not the sort of climate they're used to in Siberia, I would have thought!

Anyway, it would seem that the platter full of nitrate was me being paranoid.

I wonder if it could possibly happen, though... distributor wants to re-release classic film and buys rights, exchange/depot says "oh yes, we've got a print of that which has been sitting around for ages, hardly used at all", no-one involved in any of this knows anything about nitrate, film is delivered to multiplex and made up by inexperienced trainee...
 


Posted by Randy Stankey (Member # 64) on 09-04-2000, 07:59 PM:
 
The thing that surprises me is that the Russian State Film Archive actually let a rare / one of a kind print of ANYTHING out of their sight!

I think it'd be like pulling teeth from a grizly bear to get the American Film Institute or the Library of Congress to let a film like that out of their sight!
 


Posted by David Kilderry (Member # 142) on 09-09-2000, 03:59 AM:
 
Running nitrate on a platter is like setting a longer fuse to a bigger bomb!

I'm still amazed at what one foot of nitrate will do - burn like a gas jet. Just think what 12,000ft on a platter would do! What were they thinking - or more precisely, were they thinking at all!

Never run nitrate (at home or theatre) unless you have spool boxes, fire traps, projector door and fire extinguishers close by. Most nitrate is full of nicks and often in poor condition (its all at least 48 years old) so be careful!

I still argue that it is one of the most stable film stocks though. I have nitrate from pre 1920 still in perfect condition. Can anyone prove that acetate or polyester lasts longer - produce the goods!

David

 


Posted by Randy Stankey (Member # 64) on 09-09-2000, 08:28 AM:
 
I've never had the privilege (?) of handling nitrate film but since one of my hobbies is magic, I have played around with flash cotton. (Isn't it basically the same substance as nitrate film, just in a less refined form?)

If it's anything like flash cotton, WOAH!!!! If a platter full of nitrate ever went up, I bet it'd be like the Fourth of July!!!!!


 


Posted by Scott Norwood (Member # 30) on 09-09-2000, 09:49 AM:
 
I have the leader and tail of a nitrate trailer--maybe a total of 3 feet--at home, and this is all the nitrate that I ever want to have in my posession. The film itself was in good condition, made in 1950, not terribly shrunken. For amusement value, I burned a couple of frames once; it took longer than expected to ignite, but once it caught, it went up instantaneously.
 
Posted by Leo Enticknap (Member # 534) on 09-09-2000, 12:29 PM:
 
The British Navy made an instructional film called 'This Film is Dangerous' in the 1940s, for training sailors in the handling of nitrate stock (it was used on ships for surveillance filming etc. during the war).

One scene in the film shows a 1,000ft roll being set on fire. It's like a car petrol tank going up - even the sailor who lit the end (he'd unrolled about 20 feet of it laid out flat, which he then used as a 'fuse' to light) had to take several steps back - presumably because of the force of the heat.

In this country it's illegal to have nitrate on any premises to which the public are admitted without a special licence from the local authority. To my knowledge, the National Film Theatre and the Imperial War Museum (both in London) are the only cinemas which have one.

So even if you do have fire traps, spool boxes, liquid cooled gates and fireproof, automatically lowered porthole covers, you still can't show nitrate unless the government lets you.
 


Posted by Stefan Scholz (Member # 147) on 09-09-2000, 12:47 PM:
 
Simelar appöies to Germany. By law owning, handling, storaging and screening of nitrate films requires a special permit. Theatres to show nitrate must have all the safety and building codes fullfilled, normally not even federal archives's theatre has this, as they use Kinotone equipment.
The projectionist maust have a special "A" permit...
... and also specified is: SAFETY stock must be marked every fourth perf hole on the operator's side with a tiny punched dot, "S" or a printed black dot to give an easy means of discrimination of Nitrate stock to film - handlers. This still applies, so Digital - Dolby occupies an illegal spot on film. ...
Theoreticly anybody handling nitrate (or any film with the above mentioned safety marks)without permission (collectors!) is threatened by 2 years of imprisonment. ???!!

 
Posted by Leo Enticknap (Member # 534) on 09-10-2000, 05:11 PM:
 
That would explain why some prints on Agfa stock I've handled have the 'S' mark every four perfs...
 
Posted by John Schulien (Member # 215) on 09-28-2000, 12:21 PM:
 
Two questions -- When did Kodak begin putting the word "NITRATE" on the edges of nitrate stock, and when did they begin using date codes on 35mm film?
 
Posted by John Pytlak (Member # 331) on 09-28-2000, 12:46 PM:
 
I have a copy of the 1952 Kodak publication "Common Causes of Damage to 35 mm Release Prints". It says "For many years film manufacturers have printed the words "NITRATE FILM" at frequent intervals along the edge of film made on nitrate base". Unfortunately, it doesn't say how many years. It certainly predates me.

The Kodak website has quite a bit of information about nitrate film:
http://www.kodak.com/US/en/motion/about/environment/nitrate.shtml http://www.kodak.com/country/US/en/motion/about/environment/booklet.shtml http://www.kodak.com/US/en/motion/support/technical/storage3.shtml#nitratea http://www.kodak.com/country/US/en/motion/support/h1/identification.shtml http://www.kodak.com/country/US/en/motion/support/h1/preservation.shtml http://www.kodak.com/country/US/en/motion/support/technical/vinegar.shtml http://www.kodak.com/country/US/en/motion/about/environment/mole.shtml

Date code information is at:

http://www.kodak.com/US/en/motion/support/dateCode.shtml

Kodak has been putting date codes on motion picture film since 1916!


------------------
John P. Pytlak, Senior Technical Specialist
Worldwide Technical Services, Entertainment Imaging
Eastman Kodak Company
Research Labs, Building 69, Room 7419
Rochester, New York, 14650-1922 USA
Tel: 716-477-5325 Fax: 716-722-7243
E-Mail: john.pytlak@kodak.com


 


Posted by Mitchell Cope (Member # 32) on 09-28-2000, 01:28 PM:
 
I've occassionally seen NITRATE films for sale on eBay and in "Big Reel". Are there any postal regulations regarding the shipment of NITRATE films?
 
Posted by John Pytlak (Member # 331) on 09-28-2000, 02:00 PM:
 
Cellulose Nitrate film is considered a hazardous material, and should NEVER be sent by mail or air carrier!!! In the USA, you need to meet stringent Department of Transportation (DOT) regulations to even ship it by truck. In effect, it is treated as an EXPLOSIVE material. You are subject to severe criminal and civil penalties if you don't properly declare, label and ship hazardous materials like nitrate film.

Kodak publication H-182 has the information: http://www.kodak.com/country/US/en/motion/about/environment/booklet.shtml

BTW, anyone with nitrate film should contact a recognized film archive to see if it is rare and needs to be preserved. NEVER store nitrate film in occupied or public buildings. Only approved nitrate film vaults should be used. Storing nitrate film in a home or theatre is likely to void any fire or liability insurance you have.

To show the dangers involved with nitrate film, here is the tragic story of the "Cleveland Clinic Fire" in 1929:
http://www.ccf.org/act/frames/chp3/chp3_1.htm
http://www.ccf.org/act/frames/chp3/chp3_2.htm

------------------
John P. Pytlak, Senior Technical Specialist
Worldwide Technical Services, Entertainment Imaging
Eastman Kodak Company
Research Labs, Building 69, Room 7419
Rochester, New York, 14650-1922 USA
Tel: 716-477-5325 Fax: 716-722-7243
E-Mail: john.pytlak@kodak.com
 


Posted by John Schulien (Member # 215) on 09-29-2000, 10:43 AM:
 
Well, one of my little mysteries is solved. I have a 35mm 100' clip from an unknown silent movie. I was looking at an incomplete Kodak date chart and wondering why a silent film would have a date code of single-square, 1937.

The answer: It isn't 1937 ... It's 1917!

The inner two feet are destroyed -- the emulsion has disintegrated, but the rest of the film images are intact; it's still very flexible, not brittle at all, no emulsion tackiness outside of the inner two feet, with little sprocket damage. The film has shrunk about 2%. (I laid it over a piece of new film, and the 49th hole on the nitrate lines up with the 48th hole on the estar.)

Yes, I know to keep this film cool, dry, well ventilated, and never to project it!

- John
 


Posted by John Pytlak (Member # 331) on 09-29-2000, 11:04 AM:
 
John Schulien: Your short roll of an "unknown" movie could be just what some film archive is looking for! With really old film, it's always good to contact a recognized film archive to see if it's rare footage:
http://www.afionline.org/preservation/about/links.html

Maybe you have one of the ten "lost classic" films that the American Film Institute is looking for:
http://www.irsmarketing.com/adventures/Frankenstein/may5th.htm

------------------
John P. Pytlak, Senior Technical Specialist
Worldwide Technical Services, Entertainment Imaging
Eastman Kodak Company
Research Labs, Building 69, Room 7419
Rochester, New York, 14650-1922 USA
Tel: 716-477-5325 Fax: 716-722-7243
E-Mail: john.pytlak@kodak.com
 


Posted by Stephen Furley (Member # 1277) on 06-11-2002, 08:18 AM:
 
"Running nitrate on a platter is like setting a longer fuse to a bigger bomb!
I'm still amazed at what one foot of nitrate will do - burn like a gas jet. Just think what 12,000ft on a platter would do! What were they thinking - or more precisely, were they thinking at all!

Never run nitrate (at home or theatre) unless you have spool boxes, fire traps, projector door and fire extinguishers close by. Most nitrate is full of nicks and often in poor condition (its all at least 48 years old) so be careful!"

I would be very surprised indeed if nitrate has never been run on a platter. These things have now been around for a long time, and I'm sure that it must have happened from time to time. While the probability of a nitrate print igniting while being projected is low, the consequenses if it did happen while being run on a platter in a modern box (booth), would be so serious, as to not bear thinking about. I am not sure if the risk of this happening is increasing, or reducing; There are less nitrate prints around today, but there are also few projectionists who work with nitrate, or who have ever seen any, and therefore, there is a greater chance that a nitrate print could slip through without being spotted, if one did turn up. I recently had through my hands a nitrate short, which had about 30 feet of junk spliced on to the head. I can think of no reason to do this, other than to run it from a platter, I cannot be certain, but I think this print had been run this way at some time.

I did just once have an unexpected nitrate print delivered, and it was what is supposed not to exist; a nitrate 16mm print. This was about 20 years ago, when I was working as a technician in a school. Something didn't seem quite right about this print when I inspected it, it smelt a bit odd, and didn't feel quite right. I didn't think of nitrate at first, you don't expect it with 16mm, but I was not happy about this print, and eventually I tested a clipping from it. I had great difficulty geting the film library to believe me when I 'phoned them, but in the end they did, and I was right. This print was of Russian origin, and another similar one in the library was on safety stock. I suspect that a roll of the wrong stock was put through the 16mm slitter/perforator in error, at a time when the same factory was producing both.

This print had been around for decades, and would have been projected many times, under quite unsuitable conditions, without mishap, but it is possible that it could have ignited, and a nitrate fire, even of just a few hunderd feet, in a school classroom, would be a most serious matter.

I think that anyone who handles film today, even if they normally only see new prints, still needs to be aware of nitrate, it is still possible, if unlikely, that an old nitrate print will turn up from somewhere one day.

Nitrate film is a hazardous material, only a fool would claim otherwise, but people handle other hazardous materials, without causing major disasters. People fill their cars with petrol every day, yet you don't often hear of motorists incinerating themselves by doing this. I would consider petrol to be more dangerous than nitrate, it is a liquid, is highly volatile, and the vapor ignites very easily. If somebody sranding in a room full of people were to drop a roll of nitrate film, not a lot would happen. If the same person were to spill a litre of petrol it would stread out over a large area, this, combined with the high volatility, would result in a high concentration of vapor in the air, chich could travel a considerable distance to a source of ignition, which could be nothing more than a small spark, yet people who handle petrol every day, and think nothing of it, are terrified at the thought of nitrate film. I would certainly not store nitrate at home, (nor would I store cans of petrol), I have worked on it at home, a single reel reel at a time, but always remove it before going to bed. Providing it is in good condition, a properly equipped projection box is used, and all reasonable precautions are taken, nitrate film can be projected without undue risk, there used to be thousands of theatres doing it every night, and serious fires were not common.

I see no risk why this should not be done today. Sadly, it is now almost impossible, at least here in the uk, to find anywhere that can still do this. If we totally ban the projection of nitrate, then it will be quite impossible to see processes such as cemented Technicolor which look quite different in their original form to a modern chromogenic dupe.

"I still argue that it is one of the most stable film stocks though. I have nitrate from pre 1920 still in perfect condition. Can anyone prove that acetate or polyester lasts longer - produce the goods!"

I too have seen nitrate of this age, and older, which looked as good as new. On the other hand, in the early '70s I saw a roll of late nitrate, then only about twenty years old, and it was little more than sticky dust. I think that good quality nitrate, well processed, and stored under good conditions is at least as good as diacetate and triacetate in this respect, and probably better. As for polyester, I don't think anyone knows for sure, it hasn't been around long enough. Everyone thought triacetate was far more stable than nitrate didn't they, then we got a nasty shock.

As for the other on-going debate about nitrate, that of it looking better than safety stocks, I am not convinced; but am prepared to be so, if someone presents better evidence than I have seen so far. I recently projected several samples of nitrate, diacetate, triacetate and polyester film, the best examples of each that I could find all looked very good. The diacetate was 16mm, as I was unable to find any 35mm on this base, all other film was 35mm, and all was black and white. Projection of both guages was by carbon arc, on the same screen. I have seen good and bad nitrate, the same with safety.

One possible reason I can think of for the good reputation which nitrate has is this: The final demise of nitrate stock came at about the same time as the introduction to general use of Eastmancolor, and other similar, chromgenic stocks. Within just a few years of this, colour had become very much the norm for feature film production, black and white being mainly used for low-budget work, newsreels, television etc. I am now 45, and I can only remember seeing one or two new feature films in the cinema, not including a few made in more recent times for reasons of artistic choice. Most of the black and white material I saw was of poor quality, newsreels, low contrast telecine prints, poor video transfers and 16mm prints shown at school which were in very poor condition, and should have been scrapped years, if not decades, before. To make matters worse, these were projected with dim tungsten lamps.

I think that many people have only seen poor quality black and white film, several people have been amased when I have shown them what it can look like, and it can look very good, whatever base the stock is on. Could it be that good quality black and white largely died out at about the same time as nitrate, and that what people are seeing as an advantage of nitrate is, in fact, rather an advantage of older film, which just happens to be nitrate because of its age?

With television having converted to colour many years ago, 16mm projection in schools etc. now largely a thing of the past, and black and white no longer cheaper than colour, we are now seeing monochrome as 'art', its status has changed, and we are now more likely to see good prints than we have been for many years. Some recent prints which I have sen of classic films, on polyester stock, have looked very good indeed.


 


Posted by Mitchell Cope (Member # 32) on 06-11-2002, 09:23 AM:
 
Stephen said,
quote:
I did just once have an unexpected nitrate print delivered, and it was what is supposed not to exist; a nitrate 16mm print.... This print was of Russian origin, and another similar one in the library was on safety stock. I suspect that a roll of the wrong stock was put through the 16mm slitter/perforator in error, at a time when the same factory was producing both.

It probably was not an error. 16mm nitrate film stock was supposedly common in Russia.
 


Posted by Stephen Furley (Member # 1277) on 06-11-2002, 11:39 AM:
 
"It probably was not an error. 16mm nitrate film stock was supposedly common in Russia."

Have you ever seen such a print? I too have heard the reports of 16mm nitrate stock being used in Russia, but I have seen many Russian 16mm prints, and have never come across another nitrate one. The film library checked all their other Russian prints, they had a number of others, all of which were safety, including another copy of the same title. When I was in Russia myself in 1974, I saw film being projected in a number of exhibitions etc., which, had they been in this country, would probably have used 16mm, but all of these were 35mm.

I don't think that Nitrate was as commonly used as the rumors suggest. All I can be certain of is that at least one such print did exist. I think it is more likely that such prints were made, either in error, or due to a shortage of safety stock from time to time, Russia was well known for shortages of just about everything at various times, and some factory worker being under pressure to supply an order for 16mm thinking that they could get away with using nitrate, and nobody would notice.

While I was in Moscow, I did manage to visit the projection box of a cinema, and it was fully equipped as I would expect to see in a British box built for nitrate. The Russians were clearly aware of the dangers of nitrate; I really doubt that it was normal practice to make 16mm prints on nitrate stock, but I cannot be certain about this.

It is worrying that the print I found had been in circulation for twenty years or more, and had been projected in many schools during that time, without anybody discovering the fact. You could probably not expect teachers, and other staff in schools, to be aware of nitrate film, but this should have been picked up by the film library when the print was taken into stock; I don't know where it came from, whether it was supplied new from Russia, or if they obtained it used, from another source. I suppose that nobody expects to find 16mm nitrate, and that therefore they do not bother to look for it.

To repeat what I said in my previous post, I think that everyone who handles film today should still be aware of nitrate, and that no film which is old enough for there to be any possibility of it being nitrate, or which is of unknown age should ever be assumed to be safety, nor should edge markings be relied upon to identify a film stock.

Someone starting work today in a modern multiplex may think they will never see a nitrate print; they probably never will, but there is always the possibility of something odd, like a private hire by a company for some special event, where they supply film from their own archive. Under these circumstances a nitrate print could, just possibly, turn up.

 


Posted by Gerard S. Cohen (Member # 994) on 06-11-2002, 05:19 PM:
 

When I began theatrical projection in 1970, all theatres showing 35mm film had safety shutters, enclosed projectors and magazines, separate
power and rewind rooms, etc. Many had steel vented film vaults , with pans of water and vent ducts to the outside (check out the 1934
Neumade catalog for photos of those used in Radio City Music Hall.)
This was in New York City, where all projectionists were licensed
by the Department of Water and Electricity after passing a three-part
written, problem-solving and performance test that included electrical
wiring and fire safety. All operators were unionized, usually after
completing a months-long schooling taught by union members at a vocational school location. Thus we were authorized to run nitrate film, and the booths were licensed and inspected to permit it.
However, I never had occassion to run nitrate film in a theatre.

I remember the day when a partner at a 42nd Street Theatre informed me
that a tech was coming to remove the enclosed film magazines that were
no longer required by law, and that we would be able to run 6000' reels from open spindles.

Robert Sprague sent me a copy of a one-page historic memo from the Fire Underators, permitting the use of open reels in a theatre running
safety film. That single page became the death certificate of many single-screen theatres, and opened the floodgates to the deluge of multi-and giga-plexes that followed.

As a child playing in the streets, one kid would supply us with
nitrate film (I remember inages of Chaplin and Rin-Tin-Tin on them)
and showed us how to roll a couple of feet in newspaper,and twist the edges tight like a party-favor. Then one would light the paper with a match, the rest would run back, and the lighter would run forward
when the film ignited, and stamp it out, whereupon blue-brown smoke would pour out with a most noxious odor. We called them "stink bombs" (I later learned they were used in political and labor conflicts.) Poor-boy fireworks, perhaps, innocently if dangerously
used by us, although an older boy was arrested for throwing one into a candy store.

Once in an old booth on 42nd Street I found a rusted 100' film can
under a film vault. The nitrate film inside had completely deteriorated into a brown powder with an unforgettable aroma...
 


Posted by Steve Guttag (Member # 268) on 06-12-2002, 09:56 AM:
 
As scary as it may sound...

I know of a few people that collect, store, handle and even project nitrate film. Two of them have varified that Film-Guard is safe on Nitrate too.

Apparantly, one of the keys to nitrate film is to air it out periodically and not let the gasses build up in the can (and never seal the cans).

I can tell you, I've seen nitrate on a platter (just a short, not a feature length) and it wasn't the brightest move I've ever seen(...then again anything on a platter isn't a bright idea, but that is just me ).

While nitrate can certainly be the makings of a disaster, it certainly isn't the guaranteed fire starter some make it out to be. It definately has a look that I find more pleasing than any of today's stocks...color or B&W.

Steve

------------------
"Old projectionists never die, they just changeover!"
 


Posted by Greg Mueller (Member # 17) on 06-12-2002, 10:18 AM:
 
I had a friend who's job it was, to dispose of the Nitrate film that was used in the cameras in the planes durring WWII. I guess they were the wing cameras and aerial recon cameras. Him and his assistant would load the film into the back of the pickup and haul it out to a big pit and burn it. One day they were hauling a load to the pit and one of them was having a smoke. Apparently the cigarette somehow made it into the back of the pickup. When they discovered they were on fire they abandoned their vehicle...quickly. He said the fire was so intense it melted the back end of the pickup. He swears this is a true story
 
Posted by Gerard S. Cohen (Member # 994) on 06-12-2002, 10:42 AM:
 
Greg:
All the wing cameras I have seen used a GSAP EK/B&H 16mm film cartridge, which I think was always loaded with safety film.
But in the early days of WWII 35mm was used in B&H Filmo 70 cameras
for recon from within the fusilage. And aerial mapping still cameras
using very wide roll films may have used nitrate stock.
I had a 16mm GSAP wing camera mounted on a pistol grip with two
3" diameter cross-hairs viewing sights, running off the 24V DC supply.
on a 12' cable, that was sold with the effects of a WWII Air Force
officer.
John:
Many years ago I purchased a 1946 all-Black-cast jazz film, ("Boy, What a Girl") on nitrate stock in shipping cans, that had to be shipped via Railway Express, since other carriers wouldn't handle nitrate film.
--Gerard

 
Posted by John Pytlak (Member # 331) on 06-12-2002, 10:54 AM:
 
Another name for nitrocellulose is guncotton:
Guncotton Video
Nitrocellulose
Plastics Chemistry Lesson

------------------
John P. Pytlak, Senior Technical Specialist
Worldwide Technical Services, Entertainment Imaging
Research Labs, Building 69, Room 7525A
Rochester, New York, 14650-1922 USA
Tel: +1 585 477 5325 Cell: +1 585 781 4036 Fax: +1 585 722 7243
e-mail: john.pytlak@kodak.com
Web site: http://www.kodak.com/go/motion


 


Posted by Leo Enticknap (Member # 534) on 06-13-2002, 04:22 AM:
 
Steve: It's actually quite difficult to ignite nitrate. On a couple of occasions I have 'disposed of' reels that had decomposed beyond the point at which it would be possible to dupe them by burning them in a car park. Even with stock that has already gone volatile, you need to hold the match against the end of the film for 2-3 seconds before it catches. I suspect it's pretty unlikely that a static spark would actually ignite it, though I have no wish to be the one to find out! Prolonged stationary exposure to the light from a xenon (e.g. following a film path jam) would surely do it, though.

Stephen: Point taken about never letting your guard down - as I mentioned in the 'nitrate vs. newer stocks' thread, a film originated on safety negative or duplicated through safety intermediate stock can end up being printed on nitrate release print stock, hence confusing edge marks. However, given that the stuff has a finite lifetime there will come a point when the only nitrate left is in the care of professional archivists, and theoretically there will come a point when it's all gone. I've posted a 1951 guide to identifying nitrate from on that thread. Here is what the International Federation of Film Archives has to say on the matter:

quote:

7.5.1.a Edge Markings. For decades, film with an acetate [or polyester] base has been marked 'safety' on one or both edges of the film [by 'edge' I presume they mean the space between the perforations and the outer edge of the film surface], outside the perforations. However, you should treat this information with some caution because the marks could have been printed through from an earlier generation with a different base.

7.5.1.b Float test. The organic and toxic liquid trichloroethylene has a specific gravity between that of acetate and that of nitrate film. That means that while a small piece punched from a nitrate film will sink, a punching of acetate film will float on the surface of the trichloroethylene. However, the test is not completely reliable.

7.5.1.c Burning test. The commission does not recommend this method because it can be unreliable and unsafe, and because it consumes the film.

7.5.1.d Ultraviolet flourescence. Certain manufacturers, such as Kodak, incorporate a small amount of a flourescent chemical in the acetate film base - and this will flouresce when viewed under ultraviolet light.

Source: FIAF Preservation Commission, Preservation of Moving Images and Sound (ed. Henning Schou), pp. 36-37.


The float test is by far the most reliable, though I would not recommend the use of trichloroethylene in any environment other than a fume cabinet. There is a possibility that it could be carcinogenic.

Finally, I believe that Russian and Chinese 16mm nitrate is one of the topics covered in a new book being published next month on the history of nitrate, edited by Roger Smither of the Imperial War Museum film archive. I'll post details as soon as it's out. The Chinese certainly used it - I've seen a 16mm nitrate print of The Green River Flows East.


 


Posted by James Robertson (Member # 888) on 06-13-2002, 05:34 AM:
 
I must be one of the unlucky one who has experienced a nitrate fire in a projector.Back when I was an apprentice we used to run the occasional one off screening on Sundays. The prints were usually in shocking condition and sometimes on nitrate stock.

We were running Last of the Mohicans(no not the 1992 version Doris)
I had just completed a changeover when the film broke and all hell broke loose.The resulting fire was very intense but the fire trap did it's job and only the film in the picture head went up.
Unfortunately the other projectionist grabbed a bucket of sand and chucked that in the projector:eek(probably unnecessarily) as it would have just fizzled out.

The projector(Super Simplex) was thoroughly overhauled but never ran as sweetly ever again.

 


Posted by John Hawkinson (Member # 1135) on 06-13-2002, 01:05 PM:
 
Leo,

My understanding was that it's not legal to manufacture trichloroethane (CFCs), and so its probably pretty expensive to purchase, no?

On the other hand, it seems that you can buy it from the VWR Scientific catalog ($60/liter), though it says "Requires special licensing for purchase." I suppose that's lab grade, and one might want to thin it before use (with what?)...

--jhawk
 


Posted by John Pytlak (Member # 331) on 06-13-2002, 01:14 PM:
 
Don't confuse "trichloroethylene", "tetrachloroethylene" and "1,1,1-trichloroethane" --- they are all different chemicals.


------------------
John P. Pytlak, Senior Technical Specialist
Worldwide Technical Services, Entertainment Imaging
Research Labs, Building 69, Room 7525A
Rochester, New York, 14650-1922 USA
Tel: +1 585 477 5325 Cell: +1 585 781 4036 Fax: +1 585 722 7243
e-mail: john.pytlak@kodak.com
Web site: http://www.kodak.com/go/motion


 


Posted by Stephen Furley (Member # 1277) on 06-13-2002, 05:05 PM:
 
"Stephen: Point taken about never letting your guard down - as I mentioned in the 'nitrate vs. newer stocks' thread, a film originated on safety negative or duplicated through safety intermediate stock can end up being printed on nitrate release print stock, hence confusing edge marks. However, given that the stuff has a finite lifetime there will come a point when the only nitrate left is in the care of professional archivists, and theoretically there will come a point when it's all gone."

True, but I think that point is a long way away. Under good conditions, nitrate can last a long time, and I would expect there to still be plenty of it around long after I am dead and gone.

"I've posted a 1951 guide to identifying nitrate from on that thread."

Identifying nitrate is not always easy; I would not expect everyone handling film to be able to do the tests, but I would expect them to be aware of the existance of nitrate, and that old prints could be made of this material. If they did receive a print about which they had any doubts, they could refer the matter to someone more experienced.

"Finally, I believe that Russian and Chinese 16mm nitrate is one of the topics covered in a new book being published next month on the history of nitrate, edited by Roger Smither of the Imperial War Museum film archive. I'll post details as soon as it's out. The Chinese certainly used it - I've seen a 16mm nitrate print of The Green River Flows East."

Do you have any idea when this print was made? As long ago as 1912, Pathe were aware of the need to use safety stock for non-theatrical purposes when they introduced their 28mm gauge, at least for prints, I think the negs may have been nitrate.

 


Posted by Leo Enticknap (Member # 534) on 06-17-2002, 02:41 AM:
 
John H: Yes, that's quite right, trichloroethane is now verboten (at least the European Union have banned it - not sure about the situation in the US), which has had implications for the film industry as it was used in ultrasonic film cleaners. I have a colleague who bought up large quantities of the stuff just before it was removed from sale, and still has about 150 drums sitting in a basement! But as John P points out, this is not the same stuff as is used to carry out float tests.

quote:
Under good conditions, nitrate can last a long time, and I would expect there to still be plenty of it around long after I am dead and gone.

I've seen research from the last couple of years suggesting that if the temperature and humidity can be lowered to appropriate levels, good quality nitrate (as opposed to bad stuff in which the cellulose base was manufactured from wood pulp with a high acid content) probably has a lifetime measured in hundreds of years.

That having been said, very few private individuals are able to maintain those collections. Reducing the temperature and humidity individually is not too difficult, but reducing both at the same time is a technical nightmare. Most dehumidifiers work by heating up the air until the moisture content evaporates out of it: therefore in order to condition air so that it is cold and dry, you need to dehumidify it and then cool it in a heat exchanger in such a way as to minimise the amount of moisture that is reintroduced. The plant needed to do this is fantastically expensive, both in terms of the capital equipment cost and running costs: I've heard that the National Film and Television Archive's vaults in Hertfordshire pay electricity bills of around £100k per year just for air handling. So I suspect the time when the only nitrate left is in the hands of archivists is probably no more than 20-25 years away, though I take your point about flagging the issue up in projectionist training.

quote:
Do you have any idea when this print was made? As long ago as 1912, Pathe were aware of the need to use safety stock for non-theatrical purposes when they introduced their 28mm gauge, at least for prints, I think the negs may have been nitrate.

Well the film (The Green River Flows East) was produced in 1948 so the print was certainly after then, though I don't know whether it dated from the film's initial release or was made later.

28mm negatives were indeed nitrate, with release prints on diacetate. My memory is sketchy on this but I believe the perforations were designed in such a way as to make it physically impossible to run nitrate elements on a domestic projector - they had four perfs per frame on one side and only one on the other, against the frame line - or something like that.

When the 16mm format was launched in 1923 George Eastman himself prohibited the manufacture of any non-safety base, stating that it nitrate must be kept out of the hands of amateurs. The quote and its source can be found in Brian Winston's book 'Technologies of Seeing' (London, 1998). The Eastern Bloc, it seems, didn't take any notice.
 


Posted by John Pytlak (Member # 331) on 06-17-2002, 10:03 AM:
 
The Image Permanence Institute (IPI) at the Rochester Institute of Technology has published quite a bit of their work on film base preservation. Maintaining a low relative humidity in the storage environment and reducing temperature significantly reduce the hydrolysis reaction that causes degradation of both nitrate and acetate base materials. Venting or adsorbing any buildup of acid vapors is also very crucial.

The IPE has an on-line "Preservation Calculator":
http://www.rit.edu/~661www1/sub_pages/8contents.htm

Kodak Molecular Sieves may be used to adsorb acid vapors and control film moisture content during storage in sealed containers:
http://www.kodak.com/country/US/en/motion/support/technical/molecular.shtml
http://www.kodak.com/country/US/en/motion/support/technical/vinegar.shtml
http://www.kodak.com/US/en/motion/support/technical/storage1.shtml


------------------
John P. Pytlak, Senior Technical Specialist
Worldwide Technical Services, Entertainment Imaging
Research Labs, Building 69, Room 7525A
Rochester, New York, 14650-1922 USA
Tel: +1 585 477 5325 Cell: +1 585 781 4036 Fax: +1 585 722 7243
e-mail: john.pytlak@kodak.com
Web site: http://www.kodak.com/go/motion


 


Posted by Leo Enticknap (Member # 534) on 06-18-2002, 02:23 AM:
 
Making the right decision between which elements you vent and which ones you seal with molecular sieves within a single vault is also crucial, especially with a collection of acetate elements in various stages of decomposition. I've seen a number of instances reported in the Journal of Film Preservation (mainly from sub-tropical countries) of off-gases from vented autocatalytic elements affecting other more stable elements, which as a result have gone from Ph 6-7 on an a/d strip to Ph 4 or less within the space of a few months. If you have limited vault space and are not able to separate elements in different stages of decomposition, this can be quite a tricky decision.
 
Posted by Bernard Tonks (Member # 809) on 06-18-2002, 05:17 AM:
 
quote:
28mm negatives were indeed nitrate, with release prints on diacetate. My memory is sketchy on this but I believe the perforations were designed in such a way as to make it physically impossible to run nitrate elements on a domestic projector - they had four perfs per frame on one side and only one on the other, against the frame line - or something like that.

Leo,

If you search 28mm Film & Projectors in FHF you will find a sample of 28mm film.


 


Posted by John Pytlak (Member # 331) on 06-18-2002, 08:07 AM:
 
Leo said: "I've seen a number of instances reported in the Journal of Film Preservation (mainly from sub-tropical countries) of off-gases from vented autocatalytic elements affecting other more stable elements, which as a result have gone from Ph 6-7 on an a/d strip to Ph 4 or less within the space of a few months."

If vented film storage containers are used, it would be prudent for the vault rooms to either have high air turnover, or use carbon adsorption to help remove acid vapors from the circulating air. Segregating deteriorating rolls should also be part of that strategy.

------------------
John P. Pytlak, Senior Technical Specialist
Worldwide Technical Services, Entertainment Imaging
Research Labs, Building 69, Room 7525A
Rochester, New York, 14650-1922 USA
Tel: +1 585 477 5325 Cell: +1 585 781 4036 Fax: +1 585 722 7243
e-mail: john.pytlak@kodak.com
Web site: http://www.kodak.com/go/motion
 


Posted by Leo Enticknap (Member # 534) on 06-18-2002, 08:34 AM:
 
Sadly, separating stable and unstable elements is easier said than done if you only have one vault compartment each for nitrate and acetate. This is not an issue for the big national archives, but for smaller ones such as ours we simply don't have the space to 'quarrantine' autocatalytic elements.
 
Posted by Peter Hall (Member # 695) on 06-24-2002, 12:10 PM:
 
Mark -

You mentioned that the platter running Nitrate was most likely a

"....... platter model was the Chernobyl MKV............" Surely the American equivalent is the AW-3-Mile-Island ?


 






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